Follow actor William Shatner through interviews with the other actors who have portrayed starship Enterprise captains in five other incarnations of the Star Trek franchise. Shatner's subjects discuss their lives and careers before, during and after their tenure with Star Trek. With the use of conversations and archival footage, they explore the pressures, stigmas and sacrifices that accompanied their roles and their larger careers. During the process of the film and with help from the other Captains, Sir Patrick Stewart, Avery Brooks, Kate Mulgrew, Scott Bakula and Chris Pine, Shatner overcomes his disdain and learns to embrace his best known character, Captain James T. Kirk.